Stripe Radar can help prevent payment approval if the CVV verification fails. You can configure fraud prevention rules from your Stripe account.
You can block transactions from Mastercard debit and/or Visa debit cards by creating custom block rules in Stripe Radar.
From the Rules section of your Radar dashboard follow these steps:

Example 1
Mastercard debit cards:
Block if :card_funding: = 'debit' and
:card_brand: = 'mc' and
:card_country: = 'CA' and
::transaction_type:: = 'sale'
Example 2